For those only familiar with the TV show, the podcast eps are much longer, unscripted, at times not at all SFW, and frequently funnier than the show. I tried to pick densely funny episodes, but my favorites have more Andy Daly characters.

http://www.earwolf.com/episode/the-calvins-twins/
http://www.earwolf.com/episode/introducing-huell-howser/
http://www.earwolf.com/episode/this-is-not-me-this-is-them/
http://www.earwolf.com/episode/live-from-riot-la-2/
http://www.earwolf.com/episode/poehler-ice-caps/
http://www.earwolf.com/episode/enigma-force-five-reunion/
http://www.earwolf.com/episode/the-worlds-end/
http://www.earwolf.com/episode/halfway-to-china/
http://www.earwolf.com/episode/penises-abounding/